In this DFG funded project we study a new class of biodegradable electrets and ferroelectrets based on Polylactide Acid (PLA) and its derivatives. These have the potential of an adjustable biodegradability and suited electrical performance, i.e., sufficient charge storage and thermal charge stability. Based on our previous research, also funded by DFG (KU 3498/1-1, SE 941/21-1) and in order to obtain the energy efficient electromechanical conversion for these mechanical-based sensors, we propose using a polymer-air composite (hybrid) structure with geometrically defined air-filled and electrically charged voids. These mechanically soft hybrid systems allow achieving high piezoelectric coefficients even for very weak polar polymers such as PLA. Therefore, investigating and improving charge storage and its thermal stability is essential, since these are the most important properties to obtain high and persistent piezoelectric coefficients in biodegradable electret and ferroelectret hybrids to be used in mechanical-based sensors for quantities such as force, pressure, torque and acceleration.
Original Publication: S. Zhukov, X. Ma, H. von Seggern, G. M. Sessler, O. Ben Dali, M. Kupnik, and X. Zhang, “Biodegradable cellular polylactic acid ferroelectrets with strong longitudinal and transverse piezoelectricity”, Applied Physics Letters, vol. 117, no. 11, p. 112 901, 2020. DOI: 10.1063/5.0023153.